Nanoparticles in sustainable agriculture: An emerging opportunity.

Conventional agriculture often relies on bulky doses of fertilizers and pesticides that have adversely affected the living beings as well as the ecosystems. As a basic tenet of sustainable agriculture, minimum agrochemicals should be used so that the environment can be protected and various species can be conserved. Further, sustainable agriculture should be a low input system, where the production costs are lower and net returns are higher. The application of nanotechnology in agriculture can significantly enhance the efficiency of agricultural inputs and thus it offers a significant way to maintain sustainable development of agroecosystems via nanoparticles. In this regard, nano-plant growth promoters, nanopesticides, nanofertilizers, nano-herbicides, agrochemical encapsulated nanocarrier systems etc. have been developed for the potential applications in agriculture. These can have great benefits for agriculture, including higher production of crops, inhibition of plant pathogens, removal of unwanted weeds and insects with lesser cost, energy and waste production. However, there are several concerns related to the use of nanoparticles in agriculture. These include the approaches for synthesis, their mechanisms of penetration to applied surfaces and the risks involved. Though, advent of new technologies has significantly improved the synthesis and application of nanomaterials in agriculture, there are many uncertainties regarding nano-synthesis, their way of utilization, uptake and internalization inside the crop cells. Therefore, an elaborate investigation is required for deciphering the engineered nanomaterials, assessing their mechanistic application and agroecological toxicity. Hence, this review is aimed to critically highlight the NPs material application and points towards the vital gaps in the use of nanotechnology for sustainable agriculture.

Singh RP ，Handa R ，Manchanda G 《-》

Advancing sustainable agriculture: a critical review of smart and eco-friendly nanomaterial applications.

Undoubtedly, nanoparticles are one of the ideal choices for achieving challenges related to bio sensing, drug delivery, and biotechnological tools. After gaining success in biomedical research, scientists are exploring various types of nanoparticles for achieving sustainable agriculture. The active nanoparticles can be used as a direct source of micronutrients or as a delivery platform for delivering the bioactive agrochemicals to improve crop growth, crop yield, and crop quality. Till date, several reports have been published showing applications of nanotechnology in agriculture. For instance, several methods have been employed for application of nanoparticles; especially metal nanoparticles to improve agriculture. The physicochemical properties of nanoparticles such as core metal used to synthesize the nanoparticles, their size, shape, surface chemistry, and surface coatings affect crops, soil health, and crop-associated ecosystem. Therefore, selecting nanoparticles with appropriate physicochemical properties and applying them to agriculture via suitable method stands as smart option to achieve sustainable agriculture and improved plant performance. In presented review, we have compared various methods of nanoparticle application in plants and critically interpreted the significant differences to find out relatively safe and specific method for sustainable agricultural practice. Further, we have critically analyzed and discussed the different physicochemical properties of nanoparticles that have direct influence on plants in terms of nano safety and nanotoxicity. From literature review, we would like to point out that the implementation of smaller sized metal nanoparticles in low concentration via seed priming and foliar spray methods could be safer method for minimizing nanotoxicity, and for exhibiting better plant performance during stress and non-stressed conditions. Moreover, using nanomaterials for delivery of bioactive agrochemicals could pose as a smart alternative for conventional chemical fertilizers for achieving the safer and cleaner technology in sustainable agriculture. While reviewing all the available literature, we came across some serious drawbacks such as the lack of proper regulatory bodies to control the usage of nanomaterials and poor knowledge of the long-term impact on the ecosystem which need to be addressed in near future for comprehensive knowledge of applicability of green nanotechnology in agriculture.

Balusamy SR ，Joshi AS ，Perumalsamy H ，Mijakovic I ，Singh P ... -  《JOURNAL OF NANOBIOTECHNOLOGY》

A comprehensive overview of nanotechnology in sustainable agriculture.

Plant nutrition is crucial in crop productivity and providing food security to the ever-expanding population. Application of chemical/biological fertilizers and pesticides are the mainstays for any agricultural economy. However, there are unintended consequences of using chemical fertilizers and pesticides. The environment and ecological balance are adversely affected by their usage. Biofertilizers and biopesticides counter some undesired environmental effects of chemical fertilizers/pesticides; despite some drawbacks associated with their use. The recent developments in nanotechnology offer promise toward sustainable agriculture. Sustainable agriculture involves addressing the concerns about agriculture as well as the environment. This review briefs about important nanomaterials used in agriculture as nanofertilizers, nanopesticides, and a combination called nanobiofertilizers. Both nanofertilizers and nanopesticides enable slow and sustained release besides their eco-friendly nature. They can be tailored to the specific needs of to crop. Nanofertilizers also offer greater stress tolerance and, therefore, are of considerable value in the era of climate change. Furthermore, nanofertilizers/nanopesticides are applied in minute amounts, reducing transportation costs associated and thus positively affecting the economy. Their uses extend beyond such as if nanoparticles (NPs) are used at high concentrations; they affect plant pathogens adversely. Polymer-based biodegradable nanofertilizers and nanopesticides offer various benefits. There is also a dark side to the use of nanomaterials in agriculture. Nanotechnology often involves the use of metal/metal oxide nanoparticles, which might get access to human bodies leading to their accumulation through bio-magnification. Although their effects on human health are not known, NPs may reach toxic concentrations in soil and runoff into rivers, and other water bodies with their removal to become a huge economic burden. Nevertheless, a risk-benefit analysis of nanoformulations must be ensured before their application in sustainable agriculture.

Arora S ，Murmu G ，Mukherjee K ，Saha S ，Maity D ... -  《-》

Nanotechnology for sustainable agro-food systems: The need and role of nanoparticles in protecting plants and improving crop productivity.

The rapid population growth and environmental challenges in agriculture need innovative and sustainable solutions to meet the growing need for food worldwide. Recent nanotechnological advances found its broad applicability in agriculture's protection and post-harvesting. Engineered nanomaterials play a vital role in plant regulation, seed germination, and genetic manipulation. Their size, surface morphology, properties, and composition were designed for controlled release and enhanced properties in agriculture and the food industry. Nanoparticles can potentially be applied for the targeted and controlled delivery of fertilizers, pesticides, herbicides, plant growth regulators, etc. This help to eliminate the use of chemical-based pesticides and their water solubility, protect agrochemicals from breakdown and degradation, improve soil health, and naturally control crop pathogens, weeds, and insects, ultimately leading to enhanced crop growth and production capacity in the food industry. They can be effectively utilized for nano-encapsulation, seed germination, genetic manipulation, etc., for protecting plants and improving crop productivity, safe and improved food quality, and monitoring climate conditions. Nanoparticles played a crucial role in the uptake and translocation processes, genetically modifying the crops, high seed germination, and productivity. In this article, we have reviewed some important applications of nanoparticles for sustainable agro-food systems. The need and role of nanotechnology concerning challenges and problems faced by agriculture and the food industry are critically discussed, along with the limitations and future prospects of nanoparticles.

Guleria G ，Thakur S ，Shandilya M ，Sharma S ，Thakur S ，Kalia S ... -  《-》

Recent advances in the applications of nano-agrochemicals for sustainable agricultural development.

Singh H ，Sharma A ，Bhardwaj SK ，Arya SK ，Bhardwaj N ，Khatri M ... -  《-》