Advancing sustainable agriculture: a critical review of smart and eco-friendly nanomaterial applications.

Undoubtedly, nanoparticles are one of the ideal choices for achieving challenges related to bio sensing, drug delivery, and biotechnological tools. After gaining success in biomedical research, scientists are exploring various types of nanoparticles for achieving sustainable agriculture. The active nanoparticles can be used as a direct source of micronutrients or as a delivery platform for delivering the bioactive agrochemicals to improve crop growth, crop yield, and crop quality. Till date, several reports have been published showing applications of nanotechnology in agriculture. For instance, several methods have been employed for application of nanoparticles; especially metal nanoparticles to improve agriculture. The physicochemical properties of nanoparticles such as core metal used to synthesize the nanoparticles, their size, shape, surface chemistry, and surface coatings affect crops, soil health, and crop-associated ecosystem. Therefore, selecting nanoparticles with appropriate physicochemical properties and applying them to agriculture via suitable method stands as smart option to achieve sustainable agriculture and improved plant performance. In presented review, we have compared various methods of nanoparticle application in plants and critically interpreted the significant differences to find out relatively safe and specific method for sustainable agricultural practice. Further, we have critically analyzed and discussed the different physicochemical properties of nanoparticles that have direct influence on plants in terms of nano safety and nanotoxicity. From literature review, we would like to point out that the implementation of smaller sized metal nanoparticles in low concentration via seed priming and foliar spray methods could be safer method for minimizing nanotoxicity, and for exhibiting better plant performance during stress and non-stressed conditions. Moreover, using nanomaterials for delivery of bioactive agrochemicals could pose as a smart alternative for conventional chemical fertilizers for achieving the safer and cleaner technology in sustainable agriculture. While reviewing all the available literature, we came across some serious drawbacks such as the lack of proper regulatory bodies to control the usage of nanomaterials and poor knowledge of the long-term impact on the ecosystem which need to be addressed in near future for comprehensive knowledge of applicability of green nanotechnology in agriculture.

Balusamy SR ，Joshi AS ，Perumalsamy H ，Mijakovic I ，Singh P ... -  《JOURNAL OF NANOBIOTECHNOLOGY》

Recent trends and perspectives in the application of metal and metal oxide nanomaterials for sustainable agriculture.

Sustainable ecosystem management leads to the use of eco-friendly agricultural techniques for crop production. One of them is the use of metal and metal oxide nanomaterials and nanoparticles, which have proven to be a valuable option for the improvement of agricultural food systems. Moreover, the biological synthesis of these nanoparticles, from plants, bacteria, and fungi, also contributes to their eco-friendly and sustainable characteristics. Nanoparticles, which vary in size from 1 to 100 nm have a variety of mechanisms that are safer and more efficient than conventional fertilizers. Their usage as fertilizers and insecticides in agriculture is gaining favor in the scientific community to maximize crop output. More studies in this field will increase our understanding of this new technology and its broad acceptance in terms of performance, affordability, and environmental protection, as certain nanoparticles may outperform conventional fertilizers and insecticides. Accordingly, to the information gathered in this review, nanoparticles show remarkable potential for enhancing crop production, improving soil quality, and protecting the environment, however, metal and metal oxide NPs are not widely employed in agriculture. Many features of nanoparticles are yet left over, and it is necessary to uncover them. In this sense, this review article provides an overview of various types of metal and metal oxide nanoparticles used in agriculture, their characterization and synthesis, the recent research on them, and their possible application for the improvement of crop productivity in a sustainable manner.

Hyder S ，Ul-Nisa M ，Shahzadi ，Shahid H ，Gohar F ，Gondal AS ，Riaz N ，Younas A ，Santos-Villalobos SL ，Montoya-Martínez AC ，Sehar A ，Latif F ，Rizvi ZF ，Iqbal R ... -  《-》

Facile synthesis of nanomaterials as nanofertilizers: a novel way for sustainable crop production.

Nutrient fertilization plays a major role in improving crop productivity and maintaining soil fertility. In the last few decades, the productivity of current agricultural practices highly depends on the use of chemical fertilizers. Major drawback of traditional fertilizers is their low crop nutrient use efficiency and high loss into water. Nanomaterial in agriculture is a multipurpose tool for increasing growth, development, and yield of plants. Nanotechnology facilitates the amplifying of agriculture production by reducing relevant losses and improving the input efficiency. Nanotechnology has emerged as an attractive field of research and has various agriculture applications, especially the use of nano-agrochemicals to increase nutrient use efficiency and agricultural yield. Nanofertilizers are more effective as compared to chemical fertilizers due to their cost-efficient, eco-friendly, non-toxic, and more stable in nature. Overall, this chapter focuses on synthesis of nanofertilizers through physical, chemical, and biological methods. This chapter will also explore the use of nano-enabled fertilizers to enhance the nutrient use efficiency for sustainable crop production, and global food safety.

Basit F ，Asghar S ，Ahmed T ，Ijaz U ，Noman M ，Hu J ，Liang X ，Guan Y ... -  《-》

Agriculture and environmental management through nanotechnology: Eco-friendly nanomaterial synthesis for soil-plant systems, food safety, and sustainability.

Through the advancement of nanotechnology, agricultural and food systems are undergoing strategic enhancements, offering innovative solutions to complex problems. This scholarly essay thoroughly examines nanotechnological innovations and their implications within these critical industries. Traditional practices are undergoing radical transformation as nanomaterials emerge as novel agents in roles traditionally filled by fertilizers, pesticides, and biosensors. Micronutrient management and preservation techniques are further enhanced, indicating a shift towards more nutrient-dense and longevity-oriented food production. Nanoparticles (NPs), with their unique physicochemical properties, such as an extraordinary surface-to-volume ratio, find applications in healthcare, diagnostics, agriculture, and other fields. However, concerns about their potential overuse and bioaccumulation raise unanswered questions about their health effects. Molecule-to-molecule interactions and physicochemical dynamics create pathways through which nanoparticles cause toxicity. The combination of nanotechnology and environmental sustainability principles leads to the examination of green nanoparticle synthesis. The discourse extends to how nanomaterials penetrate biological systems, their applications, toxicological effects, and dissemination routes. Additionally, this examination delves into the ecological consequences of nanomaterial contamination in natural ecosystems. Employing robust risk assessment methodologies, including the risk allocation framework, is recommended to address potential dangers associated with nanotechnology integration. Establishing standardized, universally accepted guidelines for evaluating nanomaterial toxicity and protocols for nano-waste disposal is urged to ensure responsible stewardship of this transformative technology. In conclusion, the article summarizes global trends, persistent challenges, and emerging regulatory strategies shaping nanotechnology in agriculture and food science. Sustained, in-depth research is crucial to fully benefit from nanotechnology prospects for sustainable agriculture and food systems.

Wahab A ，Muhammad M ，Ullah S ，Abdi G ，Shah GM ，Zaman W ，Ayaz A ... -  《-》

Nanoparticles in sustainable agriculture: An emerging opportunity.

Conventional agriculture often relies on bulky doses of fertilizers and pesticides that have adversely affected the living beings as well as the ecosystems. As a basic tenet of sustainable agriculture, minimum agrochemicals should be used so that the environment can be protected and various species can be conserved. Further, sustainable agriculture should be a low input system, where the production costs are lower and net returns are higher. The application of nanotechnology in agriculture can significantly enhance the efficiency of agricultural inputs and thus it offers a significant way to maintain sustainable development of agroecosystems via nanoparticles. In this regard, nano-plant growth promoters, nanopesticides, nanofertilizers, nano-herbicides, agrochemical encapsulated nanocarrier systems etc. have been developed for the potential applications in agriculture. These can have great benefits for agriculture, including higher production of crops, inhibition of plant pathogens, removal of unwanted weeds and insects with lesser cost, energy and waste production. However, there are several concerns related to the use of nanoparticles in agriculture. These include the approaches for synthesis, their mechanisms of penetration to applied surfaces and the risks involved. Though, advent of new technologies has significantly improved the synthesis and application of nanomaterials in agriculture, there are many uncertainties regarding nano-synthesis, their way of utilization, uptake and internalization inside the crop cells. Therefore, an elaborate investigation is required for deciphering the engineered nanomaterials, assessing their mechanistic application and agroecological toxicity. Hence, this review is aimed to critically highlight the NPs material application and points towards the vital gaps in the use of nanotechnology for sustainable agriculture.

Singh RP ，Handa R ，Manchanda G 《-》