Degradation of 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol (UV328) in soil by FeS activated persulfate: Kinetics, mechanism, and theoretical calculations.

2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol (UV328) is a commonly used benzotriazole ultraviolet stabilizers (BUVs) with bioaccumulative properties. Since it's stubbornly degraded in the environment, it poses significant environmental risks in soil. However, the removal of UV328 from soil is challenging, and existing treatment methods have low efficiency. This study focuses on UV328 in soil and proposes an efficient method for its removal using persulfate (PS) activated by iron sulfide (FeS). The research demonstrates that with FeS and PS dosages of 20 and 100 mM respectively, and a soil-to-water ratio of 5:1, 12 h-removal efficiency of UV328 with an initial concentration of 12 mg/kg reaches 93.0%. Furthermore, employing electron paramagnetic resonance spectroscopy and quenching experiments, key reactive oxygen species (ROSs) are identified. SO4•-, •OH, 1O2 and •O2- contribute 31.76%, 28.77%, 26.52% and 12.95%, respectively. Four main reaction pathways of amination, hydroxylation, sulfate substitution, and bond cleavage, are identified with 14 transformation products characterized. Calculated energy profiles based on density functional theory (DFT) identify the most susceptible reaction sites for different ROSs. Five different types of agricultural soils were selected to explore the impact of soil characteristics on UV328 removal. The degradation performance of natural mackinawite demonstrates the effectiveness and accessibility of raw materials. Toxicity assessments of transformation products confirm the environmental friendliness of this system. This study proposes an efficient degradation method for UV328-contaminated soil, providing scientific insights and theoretical guidance for addressing environmental removal of BUVs from soil.

Li X ，Bu Y ，Xu J ，Alfassam HE ，Rudayni HA ，Allam AA ，Pan X ，Wang Z ，Qu R ... -  《-》

Degradation of UV328 by ozone/peroxymonosulfate system: Performance and mechanisms.

Wang M ，He C ，Zhang Z ，Zhang C ，Xiong H ，Xie X ，Zhu C ，Xu Y ，Li J ... -  《-》

Degradation of Benzotriazole UV Stabilizers in PAA/d-Electron Metal Ions Systems-Removal Kinetics, Products and Mechanism Evaluation.

Kiejza D ，Karpińska J ，Kotowska U 《-》

Synergistic activation of persulfate by FeS@SBA-15 for imidacloprid degradation: Efficiencies, activation mechanism and degradation pathways.

In this work, FeS supported SBA-15 mesoporous silica catalyst (FeS@SBA-15) was synthesized successfully, characterized and first applied to persulfate (PS) activation for the degradation of imidacloprid in wastewater. The as-prepared 3.5-FeS@SBA-15 presented an impressive imidacloprid removal efficiency of 93.1% and reaction stoichiometric efficiency (RSE) of 1.82% after 5 min, ascribed to the synergetic effects of improved FeS dispersion and abundant surface sites by SBA-15. Electron paramagnetic resonance spectra and quenching experiments proved that both SO4·- and ·OH were produced in FeS@SBA-15/PS system, and SO4·- played a dominant role in the degradation process. The S2- can accelerate the cycling of Fe(III)/Fe(II) during activation and increase the steady-state concentration of Fe(II). More importantly, the constructed heterogeneous system exhibited an efficient and stable catalytic activity over a wide range of pH (3.0-9.0), temperature (283K-313K), inorganic ion (NO3-) and humic acid (1-20 mg/L). Moreover, the density functional theory calculations were conducted to predict the potential reaction sites of imidacloprid. Based on eighteen identified intermediates, four main degradation pathways were proposed: hydroxylation, dechlorination, hydrolysis, and the ring cleavage of the imidazolidine. ECOSAR analysis indicated hydroxylation and dechlorination played a key role in the detoxification of the formed compounds. These findings would provide new insights into the application of FeS@SBA-15 catalyst in wastewater treatment and the removal mechanism of imidacloprid from wastewater.

Jiang M ，Xu Z ，Zhang T ，Zhang X ，Liu Y ，Liu P ，Chen X ... -  《-》

Distribution and trophodynamics of substituted diphenylamine antioxidants and benzotriazole UV stabilizers in a freshwater ecosystem and the adjacent riparian environment.

Lu Z ，De Silva AO ，Spencer C ，Tetreault GR ，de Solla SR ，Muir DCG ... -  《-》