Spectral interpretation of late-stage mare basalt mineralogy unveiled by Chang'E-5 samples.

The western maria of lunar near-side are widely covered with late-stage mare basalts. Due to the lack of returned samples, the mineralogy of the late-stage basalts was previously speculated as having high abundance of olivine based on remote sensing observation. However, here we show that Chang'E-5 (CE-5) lunar soil samples, the ground truth from past unsampled lunar late-stage mare region, give a different interpretation. Our laboratory spectroscopic and X-ray diffraction (XRD) analyses of the CE-5 soil samples demonstrate that their special spectral signatures are representative of iron-rich high-Ca pyroxene rather than olivine. Considering the spectral and compositional similarities between CE-5 soil samples and lunar late-stage basalts, the mineralogy and petrology of CE-5 samples may be able to be generalized to entire lunar late-stage basalts. Our study would provide a constraint on the thermal evolution of the Moon, especially the young lunar volcanism.

Liu D ，Wang X ，Liu J ，Liu B ，Ren X ，Chen Y ，Chen Z ，Zhang H ，Zhang G ，Zhou Q ，Zhang Z ，Fu Q ，Li C ... -  《Nature Communications》

Mineral chemistry and 3D tomography of a Chang'E 5 high-Ti basalt: implication for the lunar thermal evolution history.

In December 2020, Chang'E-5 (CE-5), China's first lunar sample return mission, successfully collected samples totaling 1731 g from the northern Oceanus Procellarum. The landing site was located in a young mare plain, a great distance from those of Apollo and Luna missions. These young mare basalts bear critical scientific significance as they could shed light on the nature of the lunar interior (composition and structure) as well as the recent volcanism on the Moon. In this article, we investigated a CE-5 basalt sample (CE5C0000YJYX065) using a combination of state-of-art techniques, including high resolution X-ray tomographic microscopy (HR-XTM), energy dispersive X-ray spectroscopy (EDS)-based scanning electron microscope (SEM), and electron probe microanalysis (EPMA) to reveal its 3D petrology and minerology. Our results show that this sample has a fine- to medium-grained subophitic texture, with sparse olivine phenocrysts setting in the groundmass of pyroxene, plagioclase, ilmenite and trace amounts of other phases. It has an extremely high ilmenite modal abundance (17.8 vol%) and contains a significant amount (0.5 vol%) of Ca-phosphate grains. The mineral chemistry is in excellent agreement with that of Apollo and Luna high-Ti basalts. The major phase pyroxenes also display strong chemical zoning with compositions following the trends observed in Apollo high-Ti basalts. Based on current data, we came to the conclusion that CE5C0000YJYX065 is a high-Ti mare basalt with a rare earth element (REE) enriched signature. This provides a rigid ground-truth for the geological context at the CE-5 landing site and clarifies the ambiguity inferred from remote sensing surveys.

Jiang Y ，Li Y ，Liao S ，Yin Z ，Hsu W ... -  《-》

Low Ni and Co olivine in Chang'E-5 basalts reveals the origin of the young volcanism on the Moon.

Mare basalts returned by the Chang'E-5 (CE5) mission extend the duration of lunar volcanism almost one billion years longer than previously dated. Recent studies demonstrated that the young volcanism was related neither to radiogenic heating nor to hydrous melting. These findings beg the question of how the young lunar volcanism happened. Here we perform high-precision minor element analyses of olivine in the CE5 basalts, focusing on Ni and Co. Our results reveal that the CE5 basalt olivines have overall lower Ni and Co than those in the Apollo low-Ti basalts. The distinctive olivine chemistry with recently reported bulk-rock chemistry carries evidence for more late-stage clinopyroxene-ilmenite cumulates of the lunar magma ocean (LMO) in the CE5 mantle source. The involvement of these Fe-rich cumulates could lower the mantle melting temperature and produce low MgO magma, inhibiting Ni and Co partitioning into the magma during lunar mantle melting and forming low Ni and Co olivines for the CE5 basalts. Moreover, the CE5 olivines show a continuous decrease of Ni and Co with crystallization proceeding. Fractional crystallization modeling indicates that Co decreasing with crystallization resulted from CaO and TiO2 enrichment (with MgO and SiO2 depletion) in the CE5 primary magma. This further supports the significant contribution of late-stage LMO cumulates to the CE5 volcanic formation. We suggest that adding easily melted LMO components resulting in mantle melting point depression is a key pathway for driving prolonged lunar volcanism. This study highlights the usefulness of olivine for investigating magmatic processes on the Moon.

Su B ，Zhang D ，Chen Y ，Yang W ，Mao Q ，Li XH ，Wu FY ... -  《-》

Surges in volcanic activity on the Moon about two billion years ago.

The history of mare volcanism critically informs the thermal evolution of the Moon. However, young volcanic eruptions are poorly constrained by remote observations and limited samples, hindering an understanding of mare eruption flux over time. The Chang'e-5 mission returned the youngest lunar basalts thus far, offering a window into the Moon's late-stage evolution. Here, we investigate the mineralogy and geochemistry of 42 olivine and pyroxene crystals from the Chang'e-5 basalts. We find that almost all of them are normally zoned, suggesting limited magma recharge or shallow-level assimilation. Most olivine grains record a short timescale of cooling. Thermal modeling used to estimate the thickness and volume of the volcanism sampled by Chang'e-5 reveals enhanced magmatic flux ~2 billion years ago, suggesting that while overall lunar volcanic activity may decrease over time, episodic eruptions at the final stage could exhibit above average eruptive fluxes, thus revising models of lunar thermal evolution.

Tian HC ，Zhang C ，Yang W ，Du J ，Chen Y ，Xiao Z ，Mitchell RN ，Hui H ，Changela HG ，Zhang TX ，Tang X ，Zhang D ，Lin Y ，Li X ，Wu F ... -  《Nature Communications》

A dry lunar mantle reservoir for young mare basalts of Chang'e-5.

The distribution of water in the Moon's interior carries implications for the origin of the Moon1, the crystallization of the lunar magma ocean2 and the duration of lunar volcanism2. The Chang'e-5 mission returned some of the youngest mare basalt samples reported so far, dated at 2.0 billion years ago (Ga)3, from the northwestern Procellarum KREEP Terrane, providing a probe into the spatiotemporal evolution of lunar water. Here we report the water abundances and hydrogen isotope compositions of apatite and ilmenite-hosted melt inclusions from the Chang'e-5 basalts. We derive a maximum water abundance of 283 ± 22 μg g-1 and a deuterium/hydrogen ratio of (1.06 ± 0.25) × 10-4 for the parent magma. Accounting for low-degree partial melting of the depleted mantle followed by extensive magma fractional crystallization4, we estimate a maximum mantle water abundance of 1-5 μg g-1, suggesting that the Moon's youngest volcanism was not driven by abundant water in its mantle source. Such a modest water content for the Chang'e-5 basalt mantle source region is at the low end of the range estimated from mare basalts that erupted from around 4.0 Ga to 2.8 Ga (refs. 5,6), suggesting that the mantle source of the Chang'e-5 basalts had become dehydrated by 2.0 Ga through previous melt extraction from the Procellarum KREEP Terrane mantle during prolonged volcanic activity.

Hu S ，He H ，Ji J ，Lin Y ，Hui H ，Anand M ，Tartèse R ，Yan Y ，Hao J ，Li R ，Gu L ，Guo Q ，He H ，Ouyang Z ... -  《-》