Determination of soil pH from Vis-NIR spectroscopy by extreme learning machine and variable selection: A case study in lime concretion black soil.

Variable selection is widely accepted as an important step in the quantitative analysis of visible and near-infrared (Vis-NIR) spectroscopy, as it tends to improve the model's robustness and predictive ability. In this study, a total of 140 lime concretion black soil samples were collected from two towns in Guoyang County, China. The Vis-NIR spectra measured in the laboratory were used to estimate soil pH by an extreme learning machine (ELM). First, the soil spectra were treated by the optimized continuous wavelet transform (CWT), and then four spectral feature selection methods (competitive adaptive reweighted sampling, CARS; successive projections algorithm, SPA; Monte Carlo uninformative variable elimination, MCUVE; genetic algorithm, GA) were applied with ELM in the CWT domain to determine the techniques with most predictions. For comparison, The PLS and SVM models were also developed. The coefficient of determination (R2), root mean square error (RMSE), and residual prediction deviation (RPD) were used to evaluate the model performance. Based on the validation dataset, the performance of the ELM models was superior to that of the PLS and SVM models expect SPA and MCUVE. In the ELM models, the order of the prediction accuracy was GA-ELM (R2p = 0.86; RMSEp = 0.1484; RPD = 2.64), CARS-ELM (R2p = 0.84; RMSEp = 0.1565; RPD = 2.50), ELM (R2p = 0.84; RMSEp = 0.1572; RPD = 2.49), SPA-ELM (R2p = 0.84; RMSEp = 0.1589; RPD = 2.47) and MCUVE-ELM (R2p = 0.83; RMSEp = 0.1599; RPD = 2.45). The proposed method of CARS-ELM had a relatively strong ability for spectral variable selection while retaining excellent prediction accuracy and short computing time (0.39 s). In addition, the variables selected by the four methods (CARS, SPA, MCUVE and GA) indicated the prediction mechanism for pH in lime concretion black soil may be the relation between pH and iron oxides and organic matter. In conclusion, CARS-ELM has great potential to accurately determine the pH in lime concretion black soil using Vis-NIR spectroscopy.

Wang L ，Wang R 《-》

[Hyperspectral technology combined with CARS algorithm to quantitatively determine the SSC in Korla fragrant pear].

Zhan BS ，Ni JH ，Li J 《SPECTROSCOPY AND SPECTRAL ANALYSIS》

[Rapid determination of active components in Ginkgo biloba leaves by near infrared spectroscopy combined with genetic algorithm joint extreme learning machine].

Ni HF ，Si LT ，Huang JP ，Zan Q ，Chen Y ，Luan LJ ，Wu YJ ，Liu XS ... -  《-》

[Measurement of Soil Total N Based on Portable Short Wave NIR Spectroscopy Technology].

Zhang HL ，He Y 《SPECTROSCOPY AND SPECTRAL ANALYSIS》

Rapid estimation of soil water content based on hyperspectral reflectance combined with continuous wavelet transform, feature extraction, and extreme learning machine.

Soil water content is one of the critical indicators in agricultural systems. Visible/near-infrared hyperspectral remote sensing is an effective method for soil water estimation. However, noise removal from massive spectral datasets and effective feature extraction are challenges for achieving accurate soil water estimation using this technology. This study proposes a method for hyperspectral remote sensing soil water content estimation based on a combination of continuous wavelet transform (CWT) and competitive adaptive reweighted sampling (CARS). Hyperspectral data were collected from soil samples with different water contents prepared in the laboratory. CWT, with two wavelet basis functions (mexh and gaus2), was used to pre-process the hyperspectral reflectance to eliminate noise interference. The correlation analysis was conducted between soil water content and wavelet coefficients at ten scales. The feature variables were extracted from these wavelet coefficients using the CARS method and used as input variables to build linear and non-linear models, specifically partial least squares (PLSR) and extreme learning machine (ELM), to estimate soil water content. The results showed that the correlation between wavelet coefficients and soil water content decreased as the decomposition scale increased. The corresponding bands of the extracted wavelet coefficients were mainly distributed in the near-infrared region. The non-linear model (ELM) was superior to the linear method (PLSR). ELM demonstrated satisfactory accuracy based on the feature wavelet coefficients of CWT with the mexh wavelet basis function at a decomposition scale of 1 (CWT(mexh_1)), with R2, RMSE, and RPD values of 0.946, 1.408%, and 3.759 in the validation dataset, respectively. Overall, the CWT(mexh_1)-CARS-ELM systematic modeling method was feasible and reliable for estimating the water content of sandy clay loam.

Chen S ，Gao J ，Lou F ，Tuo Y ，Tan S ，Shan Y ，Luo L ，Xu Z ，Zhang Z ，Huang X ... -  《PeerJ》