Distribution, ecological risk assessment and source identification of heavy metals in surface sediments of Huixian karst wetland, China.
In this study, heavy metals including Cd, Pb, Zn, Mn, Cu, Ni, Cr, As, and Hg, in the surface sediment (0-10 cm) of the Huixian wetland in a karst region were investigated in terms of their spatial distribution, ecological risks, and possible sources. Samples were collected from 13 typical sites throughout the Huixian wetland and were analyzed via inductively coupled plasma-mass spectrometry. The results revealed that the mean concentrations of Cd, Pb, Mn, Cr, As, and Hg were higher than the background and Chinese safe standard values. Based on spatial distribution and ecological risk, the study area was differentiated into three groups of sites with the following order of risk: group 3 > group 2 > group 1. The observed concentrations fluctuated slightly with depth. However, an irregular decreasing trend in the concentration with soil depth was observed among the groups. Multivariate statistical analyses showed that the high accumulation of Cd, Pb, Zn and Cu in the sediments of group 3 sites is due to the natural ancient deposition of minerals rich in heavy metals, while the accumulation of Mn, Cr, As, and Hg is attributed to an anthropogenic origin. Agricultural activities, the use of fertilizers and, pesticides, and local automobile repair stations most probably enriched these heavy metals in the Huixian wetland sediments. Hg and Cd have the highest potential ecological risk, which follows the order Hg > Cd > Pb > As > Ni > Cu > Cr > Mn > Zn. The mean geoaccumulation index (Igeo) values of Pb (0.48) and Hg (1.12) suggested moderate contamination in the study area.
Xiao H
，Shahab A
，Li J
，Xi B
，Sun X
，He H
，Yu G
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Distribution and ecological risk assessment of heavy metals in sediments of Dajiuhu Lake Wetland in Shennongjia, China.
The rapid development of modern society has resulted in discharge of large, heavy metal quantities into wetlands that have been continuously accumulating, causing severe pollution. Dajiuhu, located in the Shennongjia Forest District of Hubei Province in China, is a wetland of significant value internationally, serving as a model wetland ecosystem with heightened scientific research value. In this study, 27 surface sediment samples from nine sub-lakes in Dajiuhu were collected in August 2020. The concentrations of Cd, Cr, Cu, Ni, Pb, and Zn in the sediments were determined. The heavy metal occurrence and speciation characteristics were analyzed by an improved BCR (European Community Bureau of Reference) extraction method. Four methods were used to evaluate heavy metals' pollution degree and ecological risk. The possible source of heavy metals was inferred using correlation analysis and principal component analysis. The heavy metal content in the lake sediments of Dajiuhu wetland was from the highest to the lowest concentration as follows: Zn [Formula: see text] Cr [Formula: see text] Ni [Formula: see text] Pb [Formula: see text] Cu [Formula: see text] Cd. The average Cd content exceeded the national nature reserve threshold values, while the other heavy metals measured were below their respective threshold values. However, due to the occurrence of Pb and Cd in different forms, they still pose certain pollution and ecological risk to the lake wetlands. On the other hand, Zn, Cr, Ni, and Cu do not pose an ecological risk in the lakes of the Dajiuhu wetland. The spatial distribution of heavy metal content in the nine sub-lakes did vary significantly. Regarding the heavy metal sources in the lake sediments, Ni, Cr, and Cu originate from natural factors, and Cd and Pb have mainly anthropogenic origins. In contrast, Zn has both natural and anthropogenic origins. This study provides further insights into the study of heavy metal pollution in lake wetlands. It provides a framework and a direction for managing heavy metal pollution in the Dajiuhu wetland.
Wang J
，Ge J
，Yang X
，Cheng D
，Yuan C
，Liu Z
，Yang S
，Guo Y
，Gu Y
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