Graphene/polyaniline/poly(4-styrenesulfonate) hybrid film with uniform surface resistance and its flexible dipole tag antenna application.

A graphene/polyaniline/poly(4-styrenesulfonate) (G/PANI/PSS)-based conducting paste is successfully fabricated by introducing a PANI/PSS nanofiller into a multilayer graphene matrix by mechanical blending. As a compatibilizer, the PSS binder increases the dispersibility, interfacial interactions, and mechanical interlocking between the multilayer graphene matrix and PANI, thereby allowing surface resistance with narrow distribution. High concentrations of this PSS binder, obtained using ex situ polymerization, further improve the adhesion of the hybrid film to a flexible substrate. The minimum surface resistance of the screen-printed G/PANI/PSS hybrid film is approximately 10 Ω sq(-1) for a 70 μm uniform thickness. When bent to angles of -30°, the flexible hybrid film exhibits an approximately 6% decrease in surface resistance. The surface resistance after 500 bending cycles increases by only 10 Ω sq(-1) , which is 14 times that of smaller, graphene-based thin films. The micropatterned, screen-printed G/PANI/PSS hybrid film is evaluated as a practical dipole tag antenna. High-resolution patterns are formed in the hybrid film by the inherently high surface tension and the properties of grains within the domain-based structure. The G/PANI/PSS-based dipole tag antenna has a bandwidth of 28.7 MHz, a high transmitted power efficiency of 98.5%, and a recognition distance of 0.42 m at a mean frequency of 910 MHz. These characteristics indicate that the G/PANI/PSS-based dipole tag antenna could be used as a signal-receiving apparatus, much like a radio-frequency identification tag, for detecting nearby objects.

Shin KY ，Cho S ，Jang J 《-》

Platinum-decorated reduced graphene oxide/polyaniline:poly(4-styrenesulfonate) hybrid paste for flexible dipole tag-antenna applications.

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Layer-by-layer self-assembly of conducting multilayer film from poly(sodium styrenesulfonate) and polyaniline.

Tang Q ，Wu J ，Sun X ，Li Q ，Lin J ... -  《-》

Fabrication of water-dispersible and highly conductive PSS-doped PANI/graphene nanocomposites using a high-molecular weight PSS dopant and their application in H2S detection.

Cho S ，Lee JS ，Jun J ，Kim SG ，Jang J ... -  《-》

Freestanding graphene paper supported three-dimensional porous graphene-polyaniline nanocomposite synthesized by inkjet printing and in flexible all-solid-state supercapacitor.

Chi K ，Zhang Z ，Xi J ，Huang Y ，Xiao F ，Wang S ，Liu Y ... -  《-》